Another Miami Vice post will be coming later tonight as my Valentine's Day gift to you, but I'm going to ease you into the past gently by going back to 2002 before I plunge you into the cool pastel and neon waters of the mid-1980s.
Catherine Irwin's "Hex" is one of the greatest country songs, and it can totally stand up to the hyperbole I just threw at it. It has a timeless world-weary Hank Williams ancient country classicism filtered through too many nights in indie-rock clubs and bars in the late '80s and '90s. This is the sound of the lights coming up at last call and the couch and cigarette mouth the next morning. This song will never age and was always older than time. YouTube again screwed the pooch, so here is a link to the song on something called MySpace.
Alternate choice: Dalek - "Forever Close My Eyes"
These guys have the verbal and lyrical flow of guys like Chuck D or Rakim in their prime with this incredible wash of sound backing it up that brings to mind Faust, Neu!, Kevin Shields, Throbbing Gristle, Harmonia, etc.